High- and Low-Valent tris-N-Heterocyclic Carbene Iron - download pdf or read online

By Carola S. Vogel

Carola Vogel’s PhD thesis specializes in the synthesis, and structural and spectroscopic characterization of the 1st excessive valent iron nitride complexes. In her interdisciplinary and collaborative study Carola additionally describes the reactivity stories of a distinct iron (V) nitride complicated with water. those experiences exhibit that quantitative yields of ammonia are given at ambient stipulations. excessive valent iron nitride and oxo species were proposed as key intermediates in lots of bio-catalytic alterations, yet formerly those species have confirmed enormously tough to isolate and examine. Iron complexes in excessive oxidation states can hence function types for iron-containing enzymes to aid us comprehend organic platforms or relief our improvement of extra effective commercial catalysts.

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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: A Study of Molecular and Electronic Structure (Springer Theses) by Carola S. Vogel


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