clarification of the structure-property courting of a given molecule is mostly easy as the features of the atomic teams and chemical bonds and the results rising from their interplay have lengthy been identified, either from theore- cal stories and various experimental effects. against this, it's always tricky to research, estimate, and account for the structure-properties dating in sup- molecules. The features of supramolecules are ruled either by way of the character of the constituent molecules and by means of their configuration whereas the features of the constituent molecules tend to be glaring as pointed out above; their configu- tions are tough to regulate, expect, and adequately estimate due to inadequate wisdom concerning the intermolecular forces. furthermore, due to the fact lots of the int- molecular forces developing supramolecules are susceptible, the supramolecular str- ture may well range reckoning on different factors, reminiscent of amendment of the molecular constitution, auxiliaries, and experimental stipulations. hence, so that it will receive supramolecules with the specified constructions and houses, theoretical investigations at the intermolecular forces and accumulation of experimental reports at the re- tionship among the supramolecular constitution and homes are either important.